Preparation of lithium molybdenum oxide bronzes by a temperature gradient flux growth technique

W. H. McCarroll; M. Greenblatt

doi:10.1016/0022-4596(84)90157-9

Preparation of lithium molybdenum oxide bronzes by a temperature gradient flux growth technique

W. H. McCarroll
, M. Greenblatt

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

Single crystals of the violet-red Li_0.9Mo₆O₁₇, violet-blue Li_0.32MoO₃, and the new blue Li_0.04MoO₃ bronzes have been grown by a temperature gradient flux growth method in evacuated quartz ampoules. Optimal growth conditions determined for each of the phases are reported. Li_0.9Mo₆O₁₇ is monoclinic, and a quasi-two-dimensional metallic conductor at room temperature, similar to K_0.9Mo₆O₁₇ · Li_0.04MoO₃ appears to be a new intercalation compound of MoO₃.

Original language	English (US)
Pages (from-to)	282-290
Number of pages	9
Journal	Journal of Solid State Chemistry
Volume	54
Issue number	2
DOIs	https://doi.org/10.1016/0022-4596(84)90157-9
State	Published - Sep 1984

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-4596(84)90157-9

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title = "Preparation of lithium molybdenum oxide bronzes by a temperature gradient flux growth technique",

abstract = "Single crystals of the violet-red Li0.9Mo6O17, violet-blue Li0.32MoO3, and the new blue Li0.04MoO3 bronzes have been grown by a temperature gradient flux growth method in evacuated quartz ampoules. Optimal growth conditions determined for each of the phases are reported. Li0.9Mo6O17 is monoclinic, and a quasi-two-dimensional metallic conductor at room temperature, similar to K0.9Mo6O17 · Li0.04MoO3 appears to be a new intercalation compound of MoO3.",

author = "McCarroll, \{W. H.\} and M. Greenblatt",

note = "Funding Information: tion measurements,a nd Dr. K. V. R. Chary for technical assistance.T he work received support from the National Science Foundation-Solid State Chemistry Grant DMR-81-15977.W . H. M. gratefully acknowledges support under the Small College Faculty Research Participation Program of NSF.",

year = "1984",

month = sep,

doi = "10.1016/0022-4596(84)90157-9",

language = "English (US)",

volume = "54",

pages = "282--290",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "2",

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TY - JOUR

T1 - Preparation of lithium molybdenum oxide bronzes by a temperature gradient flux growth technique

AU - McCarroll, W. H.

AU - Greenblatt, M.

N1 - Funding Information: tion measurements,a nd Dr. K. V. R. Chary for technical assistance.T he work received support from the National Science Foundation-Solid State Chemistry Grant DMR-81-15977.W . H. M. gratefully acknowledges support under the Small College Faculty Research Participation Program of NSF.

PY - 1984/9

Y1 - 1984/9

N2 - Single crystals of the violet-red Li0.9Mo6O17, violet-blue Li0.32MoO3, and the new blue Li0.04MoO3 bronzes have been grown by a temperature gradient flux growth method in evacuated quartz ampoules. Optimal growth conditions determined for each of the phases are reported. Li0.9Mo6O17 is monoclinic, and a quasi-two-dimensional metallic conductor at room temperature, similar to K0.9Mo6O17 · Li0.04MoO3 appears to be a new intercalation compound of MoO3.

AB - Single crystals of the violet-red Li0.9Mo6O17, violet-blue Li0.32MoO3, and the new blue Li0.04MoO3 bronzes have been grown by a temperature gradient flux growth method in evacuated quartz ampoules. Optimal growth conditions determined for each of the phases are reported. Li0.9Mo6O17 is monoclinic, and a quasi-two-dimensional metallic conductor at room temperature, similar to K0.9Mo6O17 · Li0.04MoO3 appears to be a new intercalation compound of MoO3.

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DO - 10.1016/0022-4596(84)90157-9

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AN - SCOPUS:0021498175

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JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Preparation of lithium molybdenum oxide bronzes by a temperature gradient flux growth technique

Abstract

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