Electronic properties of ultra-thin YCrO3 films

Banabir Pal; Xiaoran Liu; Fangdi Wen; Mikhail Kareev; A. T. N'Diaye; P. Shafer; E. Arenholz; Jak Chakhalian

doi:10.1063/1.5029977

Electronic properties of ultra-thin YCrO₃ films

Banabir Pal
, Xiaoran Liu
, Fangdi Wen
, Mikhail Kareev
, A. T. N'Diaye
, P. Shafer
, E. Arenholz
, Jak Chakhalian

School of Arts and Sciences, New High Energy Theory Center

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

We report on the heteroepitaxial stabilization of YCrO₃ ultra-thin films on LSAT (001) substrate. Using a combination of resonant X-ray absorption spectroscopy (XAS) and atomic multiplet cluster calculation, the electronic structure of YCrO₃ thin film was investigated. Polarization dependent Cr L_3,2 edge XAS measurements reveal the presence of x-ray linear dichroism spectrum uncharacteristic of a 3d³ electronic system in an octahedral crystal field. Atomic multiplet calculation demonstrates the critical importance of charge transfer energy, coulomb correlation strength, and hopping interaction in realizing this dichroism spectrum.

Original language	English (US)
Article number	252901
Journal	Applied Physics Letters
Volume	112
Issue number	25
DOIs	https://doi.org/10.1063/1.5029977
State	Published - Jun 18 2018

All Science Journal Classification (ASJC) codes

Physics and Astronomy (miscellaneous)

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10.1063/1.5029977

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title = "Electronic properties of ultra-thin YCrO3 films",

abstract = "We report on the heteroepitaxial stabilization of YCrO3 ultra-thin films on LSAT (001) substrate. Using a combination of resonant X-ray absorption spectroscopy (XAS) and atomic multiplet cluster calculation, the electronic structure of YCrO3 thin film was investigated. Polarization dependent Cr L3,2 edge XAS measurements reveal the presence of x-ray linear dichroism spectrum uncharacteristic of a 3d3 electronic system in an octahedral crystal field. Atomic multiplet calculation demonstrates the critical importance of charge transfer energy, coulomb correlation strength, and hopping interaction in realizing this dichroism spectrum.",

author = "Banabir Pal and Xiaoran Liu and Fangdi Wen and Mikhail Kareev and N'Diaye, \{A. T.\} and P. Shafer and E. Arenholz and Jak Chakhalian",

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T1 - Electronic properties of ultra-thin YCrO3 films

AU - Pal, Banabir

AU - Liu, Xiaoran

AU - Wen, Fangdi

AU - Kareev, Mikhail

AU - N'Diaye, A. T.

AU - Shafer, P.

AU - Arenholz, E.

AU - Chakhalian, Jak

PY - 2018/6/18

Y1 - 2018/6/18

N2 - We report on the heteroepitaxial stabilization of YCrO3 ultra-thin films on LSAT (001) substrate. Using a combination of resonant X-ray absorption spectroscopy (XAS) and atomic multiplet cluster calculation, the electronic structure of YCrO3 thin film was investigated. Polarization dependent Cr L3,2 edge XAS measurements reveal the presence of x-ray linear dichroism spectrum uncharacteristic of a 3d3 electronic system in an octahedral crystal field. Atomic multiplet calculation demonstrates the critical importance of charge transfer energy, coulomb correlation strength, and hopping interaction in realizing this dichroism spectrum.

AB - We report on the heteroepitaxial stabilization of YCrO3 ultra-thin films on LSAT (001) substrate. Using a combination of resonant X-ray absorption spectroscopy (XAS) and atomic multiplet cluster calculation, the electronic structure of YCrO3 thin film was investigated. Polarization dependent Cr L3,2 edge XAS measurements reveal the presence of x-ray linear dichroism spectrum uncharacteristic of a 3d3 electronic system in an octahedral crystal field. Atomic multiplet calculation demonstrates the critical importance of charge transfer energy, coulomb correlation strength, and hopping interaction in realizing this dichroism spectrum.

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VL - 112

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 25

M1 - 252901

ER -

Electronic properties of ultra-thin YCrO₃ films

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